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There are many ways one can go about determining the structure of an unknown organic molecule. Although, nuclear magnetic resonance (NMR) and infrared radiation (IR) are the primary ways of determining molecular structures, calculating the degrees of unsaturation is useful information since knowing the degrees of unsaturation make it easier for one to figure out the molecular structure; it helps one double-check the number of (pi) bonds and/or cyclic rings.

Saturated vs. Unsaturated Molecules

In the lab, saturation may be thought of as the point when a solution cannot dissolve anymore of a substance added to it. In terms of degrees of unsaturation, a molecule only containing single bonds with no rings is considered saturated.

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Unlike saturated molecules, unsaturated molecules contain double bond(s), triple bond(s) and/or ring(s).

Calculating Degrees of Unsaturation (DoU)

Degree of Unsaturation (DoU) is also known as Double Bond Equivalent. If the molecular formula is given, plug in the numbers into this formula:

[ DoU= dfrac{2C+2+N-X-H}{2} ]

• (C) is the number of carbons
• (N) is the number of nitrogens
• (X) is the number of halogens (F, Cl, Br, I)
• (H) is the number of hydrogens

As stated before, a saturated molecule contains only single bonds and no rings. Another way of interpreting this is that a saturated molecule has the maximum number of hydrogen atoms possible to be an acyclic alkane. Thus, the number of hydrogens can be represented by 2C+2, which is the general molecular representation of an alkane. As an example, for the molecular formula C₃H₄ the number of actual hydrogens needed for the compound to be saturated is 8 [2C+2=(2x3)+2=8]. The compound needs 4 more hydrogens in order to be fully saturated (expected number of hydrogens-observed number of hydrogens=8-4=4). Degrees of unsaturation is equal to 2, or half the number of hydrogens the molecule needs to be classified as saturated. Hence, the DoB formula divides by 2. The formula subtracts the number of X's because a halogen (X) replaces a hydrogen in a compound. For instance, in chloroethane, C₂H₅Cl, there is one less hydrogen compared to ethane, C₂H₆.

For a compound to be saturated, there is one more hydrogen in a molecule when nitrogen is present. Therefore, we add the number of nitrogens (N). This can be seen with C₃H₉N compared to C₃H₈. Oxygen and sulfur are not included in the formula because saturation is unaffected by these elements. As seen in alcohols, the same number of hydrogens in ethanol, C₂H₅OH, matches the number of hydrogens in ethane, C₂H₆.

The following chart illustrates the possible combinations of the number of double bond(s), triple bond(s), and/or ring(s) for a given degree of unsaturation. Each row corresponds to a different combination. Mac software update 10 6.

• One degree of unsaturation is equivalent to 1 ring or 1 double bond (1 ( pi ) bond).
• Two degrees of unsaturation is equivalent to 2 double bonds, 1 ring and 1 double bond, 2 rings, or 1 triple bond (2 ( pi ) bonds).

Remember, the degrees of unsaturation only gives the sum of double bonds, triple bonds and/or rings. For instance, a degree of unsaturation of 3 can contain 3 rings, 2 rings+1 double bond, 1 ring+2 double bonds, 1 ring+1 triple bond, 1 double bond+1 triple bond, or 3 double bonds.

Example: Benzene

What is the Degree of Unsaturation for Benzene?

SOLUTION

The molecular formula for benzene is C₆H_6. Thus,

DoU= 4, where C=6, N=0,X=0, and H=6. 1 DoB can equal 1 ring or 1 double bond. This corresponds to benzene containing 1 ring and 3 double bonds.

However, when given the molecular formula C₆H₆, benzene is only one of many possible structures (isomers). The following structures all have DoB of 4 and have the same molecular formula as benzene.

References

1. Vollhardt, K. P.C. & Shore, N. (2007). Organic Chemistry (5^thEd.). New York: W. H. Freeman. (473-474)
2. Shore, N. (2007). Study Guide and Solutions Manual for Organic Chemistry (5^th Ed.). New York: W.H. Freeman. (201)

Problems

1. Are the following molecules saturated or unsaturated:
   1. (b.) (c.) (d.) C₁₀H₆N₄
2. Using the molecules from 1., give the degrees of unsaturation for each.
3. Calculate the degrees of unsaturation for the following molecular formulas:
   1. (a.) C₉H₂₀(b.) C₇H₈(c.) C₅H₇Cl (d.) C₉H₉NO₄
4. Using the molecular formulas from 3, are the molecules unsaturated or saturated.
5. Using the molecular formulas from 3, if the molecules are unsaturated, how many rings/double bonds/triple bonds are predicted?

Answers

1.

(a.) unsaturated (Even though rings only contain single bonds, rings are considered unsaturated.)

(b.) unsaturated

(c.) saturated

(d.) unsaturated

2. If the molecular structure is given, the easiest way to solve is to count the number of double bonds, triple bonds and/or rings. However, you can also determine the molecular formula and solve for the degrees of unsaturation by using the formula.

(a.) 2

Caesar 3 free game. (b.) 2 (one double bond and the double bond from the carbonyl)

(c.) 0

(d.) 10

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3. Use the formula to solve

(a.) 0

(b.) 4 Mac bluray player for windows crack.

(c.) 2

(d.) 6

4.

(a.) saturated

(b.) unsaturated

(c.) unsaturated

(d.) unsaturated

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(a.) 0 (Remember-a saturated molecule only contains single bonds)

(b.) The molecule can contain any of these combinations(i) 4 double bonds (ii) 4 rings (iii) 2 double bonds+2 rings (iv) 1 double bond+3 rings (v) 3 double bonds+1 ring (vi) 1 triple bond+2 rings (vii) 2 triple bonds (viii) 1 triple bond+1 double bond+1 ring (ix) 1 triple bond+2 double bonds

(c.) (i) 1 triple bond (ii) 1 ring+1 double bond (iii) 2 rings (iv) 2 double bonds

(d.) (i) 3 triple bonds (ii) 2 triple bonds+2 double bonds (iii) 2 triple bonds+1 double bond+1 ring (iv).. (As you can see, the degrees of unsaturation only gives the sum of double bonds, triple bonds and/or ring. Thus, the formula may give numerous possible structures for a given molecular formula.)